In Path of Exile, whenever you use a skill or attack, you have a chance to deal a Critical Strike. Critical Strikes are rolled on a per-action basis, not per-monster. So each time you use a skill, the Critical Strike roll is made once and only once. If you roll a Critical Strike, you will deal Critical damage to all enemies hit by the skill.
Critical Strikes do more damage than normal, based on your Critical Strike Damage Multiplier. All characters have a base Critical Strike multiplier of 150%, meaning a critical strike does 150% of normal damage. This multiplier can be increased with various skills and modifiers on items.
For example, with a multiplier of 250%, if you deal a Critical Strike with attack that normally does 100 damage, you will instead deal 250 damage. This is not as simple as buy poe orbs.
The chance to deal a critical strike is taken from the weapon used to perform an attack or attack skill, and in the case of spells, each spell has it’s own critical strike chance, which is listed in the skill gem’s description.
This value can be increased by increased critical strike chance modifiers from spells and gear. For example, if you are using a weapon with 5% chance to crit, and you have 50% increased critical strike chance, you will have a 7.5% chance to score a critical strike.
Critical Strike Chance and Critical Strike Damage Multiplier are calculated separately for each spell and weapon attack. All weapons and damage-dealing spells have a base Critical Strike chance listed on them. This only affects your chance to critical for attacks made with that weapon or spell. For instance the base critical strike chance on a wand does not affect your chance to critical with a spell.
However, global modifiers that appear on weapons can and will affect your chance to crit with any attack or skill. They will stack additively with other mods of the same type, such as those found in the passive skill tree.
Local Critical Strike Chance modifiers affect the base critical strike chance of the weapon – the weapon’s modified crit chance will be shown in blue on the weapon’s description. This makes Critical Strike Chance modifiers that appear on weapons more valuable than other sources on a point-for-point basis.
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